Make Sure Virtual machine not in running state/mode.
After that use below command.
[root@localhost tmp]# VBoxManage internalcommands converttoraw machine-name.vdi newmachine-name.img
VirtualBox Command Line Management Interface Version 3.1.0
(C) 2005-2009 Sun Microsystems, Inc.
All rights reserved.
Converting image "umarket-oracle-1-36.vdi" with size 8589934592 bytes (8192MB) to raw...
This will take time according to Machine Size.
Once Finished, Move .img machine to running KVM machine.
Here you need to create following things.
1) newmachie-nam.xml under /ect/libvirt/qemu
2) Storage path location must be correct.
3) Machine name
4) UUID
Restart libvirtd service, after that you can find your machine under Virt-manager.
Enjoy.